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OH grupa nije dobra odlaze?a grupa u reakcijama nukleofilne supstitucije, tako da neutralni alkoholi ne reaguju u takvim reakcijama. Me?utim, ako se kiseonik prvo protonira i formira R?OH2+, odlaze?a grupa (voda) je daleko stabilnija, i nukleofilna supstitucija se može odvijati. Na primer, tercijarni alkoholi reaguju sa hlorovodoni?nom kiselinom i